Why choose a pH5 shampoo for your scalp?

What you must remember

The scalp has a natural pH between 4,5 and 5,5. The further a shampoo deviates from this, the more the hair fiber swells, the more the cuticles lift, and the weaker the skin barrier becomes. pH is the most crucial factor in a shampoo—and the only one no one advertises.

  • The scalp has a natural pH between 4,5 and 5,5
  • An alkaline pH causes the fiber to swell and the scales to lift.
  • pH 5 does not regulate sebum: it preserves the skin barrier
  • pH carries more weight than any "free from" claim.
pH5 shampoo

pH is the most crucial factor in a shampoo, and practically the only one that no one advertises. It influences the swelling of the hair fiber, the integrity of the skin barrier, and the balance of the microbiome—far more than any "free from" claim on the bottle.

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What is the natural pH of the scalp?

The scalp is skin, with a slightly acidic hydrolipidic film, located between 4,5 and 5,5. This is called the acid mantle, and it fulfills two essential functions.

  • It maintains the cohesion of the skin barrier and limits water loss
  • It creates an environment unfavorable to the proliferation of undesirable microorganisms.
  • It preserves the balance of the microbiome specific to this sebum-rich area.


pH is the criterion no one mentions, yet everyone has to put up with it. I hear about sulfates, silicones, ingredient lists—and all the while, the factor that truly determines the condition of a hair cuticle after washing doesn't appear on any label. That's why I formulate all my shampoos at pH 5.
Dr. Julie PernetDoctor of Pharmacy & Certified Trichologist

What happens when the pH of the shampoo is too high?

The further the environment deviates from its natural acidity, the more the hair fiber swells and the more the cuticle scales lift. A spiky surface catches, tangles, becomes more porous , and accumulates static electricity. On the scalp, an alkaline pH weakens the skin barrier, which promotes irritation, tightness, and flaking.

Who would benefit from a pH5 shampoo?

In practice, it applies to everyone — but the difference is dramatic for certain profiles:

  • An itchy, tight, or red scalp after shampooing
  • The dandruff recurring, dry or oily
  • Frequent washing, daily or every other day
  • Colored, bleached, or already damaged hair
  • Rough lengths that constantly tangle and frizz
  • Seborrheic dermatitis or psoriasis, where the barrier is already weakened

Before
Before
After
After

Verified review

"Impressive. I've only been using it for a month and I'm shocked: the scent is divine, the texture perfect. And from the very first application, my hair is thicker, fuller, and stronger."

Sonia D., a customer for 12 months

Discover the solution

How to choose a shampoo with a pH of 5?

The pH level is rarely indicated: the mention of "physiological pH" or "pH 5" on the bottle is a sign of transparency in itself. Next, look at the cleansing system, favoring gentle surfactants rather than a sulfate as the top ingredient. And above all, remember that the absence of an ingredient says nothing about the product's actual gentleness: a "free from" claim never tells you what has replaced it.

Natural Universal Shampoo pH5

Gently cleanses & respects the scalp microbiome

€16,90

To remember

  • The scalp has a natural pH between 4,5 and 5,5
  • An alkaline pH causes the fiber to swell and the scales to lift.
  • pH 5 does not regulate sebum: it preserves the skin barrier
  • pH carries more weight than any "free from" claim.

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F.A.Q

What is the ideal pH for a shampoo?
A pH around 5, aligned with that of the scalp which is between 4,5 and 5,5. At this level, the swelling of the fiber is minimal and the skin barrier remains intact, which allows frequent washing without irritation.
Does a pH5 shampoo regulate oily hair?
No, sebum production depends on hormones, not the pH of your shampoo. However, a pH 5 shampoo allows you to wash as often as needed without irritating the scalp—which is precisely what an oily scalp needs.
How can I determine the pH of my shampoo?
Few brands advertise it: look for the mention "pH 5" or "physiological pH" on the bottle or product information sheet. Its absence isn't a deal-breaker, but a manufacturer who understands this parameter generally has an interest in stating it.
Is a pH5 shampoo suitable for colored hair?
Absolutely. An alkaline pH causes the fibers to swell and raise the scales, which accelerates pigment loss. Washing at pH 5 limits this swelling and therefore better preserves the color.
pH5 shampoo or sulfate-free shampoo: which to choose?
The two criteria are independent. A sulfate-free shampoo can be alkaline, and a sulfate shampoo can be adjusted to pH 5. If you had to choose just one, pH has a greater impact on the condition of the cuticle and scalp.

Written by

Dr. Julie Pernet

Doctor of Pharmacy & Certified Trichologist. Doctor of Pharmacy and Trichologist, founder of the DermoPilaire MakeMyMask Laboratory. She develops skincare protocols focused on scalp health, based on microbiome science and pH balance.

Dr. Julie Pernet